Wikipedia strikes again:
The naive expectation is that, for every place on Earth, the Sun will
appear to be above the horizon for exactly half the time. Thus, for a
standard year consisting of 8760 hours, apparent maximal daytime
duration would be 4380 hours. However, there are physical and
astronomical effects which change that picture. Namely, atmospheric
refraction allows the Sun to be still visible even when it physically
sets below the horizon line. For that reason, average daytime
(disregarding cloud effects) is longest in polar areas, where the
apparent Sun spends the most time around the horizon. Places on the
Arctic Circle have the longest total annual daytime of 4647 hours,
while the North Pole receives 4575. Because of elliptic nature of the
Earth's orbit, the Southern Hemisphere is not symmetrical: Antarctic
Circle at 4530 hours receives 5 days less of sunshine than its
antipodes. The Equator has the total daytime of 4422 hours per
year.
Further details here on astronomical causes of average daytime variation, and here on Insolation, the solar radiation received at the top of the atmosphere and its effects on the energy received at ground level.
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