I think you're looking for Liouville's theorem. This theorem states that for n>2, if V1,V2subsetmathbbRn are open subsets and f:V1rightarrowV2 is a smooth conformal map, then f is the restriction of a higher-dimensional analogue of a Mobius transformation.
By the way, observe that there are no assumptions on the topology of the Vi -- they don't have to be simply-connected, etc.
EDIT : I'm updating this ancient answer to
link to a blog post by Danny Calegari which contains a sketch of a beautifully geometric argument for Liouville's theorem.
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