One simple thing that can go wrong is purely related to the size of the space (polish spaces are all size leq2aleph0). When spaces are large enough product measures become surprisingly badly behaved. Consider Nedoma's pathology: Let X be a measure space with |X|>2aleph0. The diagonal in X2 is not measurable.
We'll prove this by way of a theorem:
Let UsubseteqX2 be measurable. U can be written as a union of at most 2aleph0 spaces of the form AtimesB.
Proof: First note that we can find some countable collection Ai such that Usubseteqsigma(AitimesAj) (proof: The set of V such that we can find such Ai is a sigma algebra containing the basis sets).
For xin0,1mathbbN define Bx=bigcapAi:xi=1capbigcapAci:xi=0.
Consider all sets which can be written as a (possibly uncountable) union of BxtimesBy for some y. This is a sigma algebra and obviously contains all the AitimesAj, so contains A.
But now we're done. There are at most 2aleph0 of the Bx, and each is certainly measurable in X, so U can be written as a union of 2aleph0 sets of the form AtimesB.
QED
Corollary: The diagonal is not measurable.
Evidently the diagonal cannot be written as a union of at most 2aleph0 rectangles, as they would all have to be single points, and the diagonal has size |X|>2aleph0.
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