This is addressed by the classical invariant theory, but the answer is more complicated than for general linear or orthogonal groups (in particular, not all minimal generators are quadratic). Let k be a field of characteristic 0. The group G=SOm acts on mtimesn matrices by the left multiplication and this induces a G-action on A=k[Xij]. Let us view the variables as the entries of the mtimesn generic matrix over k. Then the algebra of invariants AG is generated by:
1 Scalar products of the columns of the matrix X.
2 Order m minors of the matrix X.
This is the First Fundamental Theorem (FFT) of classical invariant theory for SOm. In fact, the elements of the first type generate Om-invariants and the elements of the second type generate SLm-invariants (SOm=OmcapSLm).
Moreover, all relations between these generators are also known (the Second Fundamental Theorem, SFT) and there is a good description of a standard monomial basis of AG. If I am not mistaken, the last part is due to Laskshmibai and coauthors. A comprehensive modern reference is
Laskshmibai and Raghavan, Standard monomial theory. Invariant theoretic approach. Encyclopaedia of Mathematical Sciences, vol 137 (Invariant Theory and Algebraic Transformation Groups VIII), Springer.
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