I have done some courses on quantum mechanics and statistical mechanics in the past. Since I also do math, I wonder about converge issues which are usually not such a problem in physics. One of those questions is the following. I will describe the background, but in the end it boils down to a question about ordinary differential equations.
In quantum mechanics on the real line, we start with a potential V:mathbbRtomathbbR and try to solve the Schrödinger question ihbarfracpartialpartialtPsi(x,t)=−frachbar22mfracpartial2partialx2Psi(x,t)+V(x)Psi(x,t). In many cases this can be accomplished by seperating variables, in which case we obtain the equation EPsi(x,t)=−frachbar22mfracpartial2partialx2Psi(x,t)+V(x)Psi(x,t) which we try to solve for E and Psi to obtain a basis for our space of states together with an associated energy spectrum. For example, if we have a harmonic oscillator, V(x)=frac12momega2x2 and we get En=hbaromega(n+frac12) and Psin a certain product of exponentials and Hermite polynomials. We assume that the energy in normalized such that the lowest energy state has energy 0.
If the states of our system are non-degenerate, i.e. there is only one state for each energy level in the spectrum, then the partition function in statistical mechanics for this system is given by the sum Z(beta)=sumnexp(−betaEn), where beta is the inverse temperature frac1kBT. It is clear that this sum can be divergent; in fact for a free particle (V=0), it is not even well defined since spectrum is a continuum.
However, I was wondering about the following question: Is there a system such that Z(beta) diverges for beta<alpha and converges for beta>alpha for some alphainmathbbR>0? Am I correct in thinking that such a system is most likely an approximation of another system, which undergoes a phase transition at beta=alpha?
Anyway, an obvious candidate would be a potential V such that the spectrum is given En=Clog(n+1) for ngeq0 and C>0. This gets me to my main mathematical question: Does such a potential (or one with spectrum asymptotically similar) exist? If so, can you give it explicitly?
One the circle, the theory of Sturm-Liouville equations tells us that the eigenvalues must go asymptotically as Cn2, so in this case such problems can't occur. I don't know much about spectral theory for Sturm-Liouville equations on the real line though. The second question is therefore: What is known about the asymptotics of the spectrum of a Sturm-Liouville operator on the real line?
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