This is not a complete answer by any means, but is intended to get the ball rolling.
First of all, it need not be the case that H1(Xfl,mun)=0. Rather, what follows
from the vanishing of H1(Xfl,mathbbGm) is that
H1(Xfl,mun)=Rtimes/(Rtimes)n.
(This is not always trivial; imagine
e.g. that R is a non-algebraically closed field. You might have been thinking of the case
when X is projective and smooth over an algebraically closed field, when the H0-part of the exact sequence is itself exact, and so can be omitted from consideration. That is not the case here.)
Secondly, this doesn't hurt your arguments, because the same consideration of H0-terms has to be made for the cohomology of U. Since X is three dimensional and a complete intersection, restriction induces an isomorphism
H0(X,mathcalO)congH0(U,mathcalO), and so also an isomorphism
H0(X,mathcalOtimes)congH0(U,mathcalOtimes), and so also isomorphisms
H0(Xfl,mun)congH0(Ufl,mun) and
H0(Xfl,mathbbGm)congH0(Ufl,mathbbGm). Thus in fact one finds that
the n-torsion in Pic(U) is equal to the cokernel of the injection
H1(Xfl,mun)hookrightarrowH1(Ufl,mun). And as your analysis shows, this cokernel embeds into H2m(Xfl,mun), with the cokernel of that embedding itself embedding into H2(Xfl,mun).
So what can be said about this latter cohomology group?
Since H1(Xfl,mathbbGm) vanishes, as you observed, one finds that H2(Xfl,mun) coincides with the n-torsion in the cohomological Brauer group H2(Xfl,mathbbGm). (Here I am using the fact that since mathbbGm is smooth, flat and etale cohomology coincide, so H2(Xfl,mathbbGm)=H2(Xet,mathbbGm).) So it seems that one wants to kill off the torsion in this Brauer group.
I don't see why this need be true, but what one actually needs is that H2(Xfl,mun)rightarrowH2(Ufl,mun) is injective. Since H2(Xfl,mun) embeds into
H2(Xfl,mathbbGm), it would be enough to show that the restriction
H2(Xfl,mathbbGm)toH2(Ufl,mathbbGm) induces an injection on torsion. Might this be some kind of purity result on Brauer groups of the kind Gabber discusses in his abstract? It would be related to a vanishing of (torsion in) H2m(Xfl,mathbbGm). Somewhere (maybe here?) one presumably has to make use of the dimension and lci hypotheses.
P.S. You may well just want to email Gabber to ask him about this. If you do, and you get an answer, please share it!
EDIT: This is an excerpt from the email referred to in Hai Long's comment below:
To learn about these kinds of arguments, my advice is to
do just what you are doing. One works with the exact sequence
linking mun and mathbbGm, as you did.
Number theorists (at least of a certain stripe) have some advantages
with this, because the case X= Spec K (K a field) comes up a lot
under the name of Kummer theory, and also Mazur in one of his
famous papers uses a lot of flat cohomology. But in the end, the
formalism is just the one you used in your question.
Then, typically, one has to inject something additional that
is less formal. My suggestion would be to look at de Jong's proof
of Gabber's result showing Br′(X)=Br(X) discussed in his abstract.
(There is a write-up on de Jong's web-page.)
Reading the proof of a result like this might give some insight
into how to work with Brauer groups in a less formal way.
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