Let me try to give a counterexample. (I don't know whether it is 'nice'). First, let us rewrite your properties for an affine scheme X=Spec(A).
Connectedness for A means A has no nontrivial idempotents;
Integrality for A is the usual one (A is a domain);
Local integrality means that whenever fg=0 in A, every point of X has a neighborhood
where either f or g vanishes.
Let us construct a connected locally integral ring that is not integral.
Roughly speaking, the construction is as follows: let X0 be the cross (the union of coordinate axes) on the affine plane. Then let X1 be the (reduced) full preimage of X0 on the blow-up of the plane (X1 has three rational components forming a chain). Then blow up the resulting surface at the two singularities of X1, and let X2 be the reduced preimage of X1
(which has five rational components), etc. Take X to be the inverse limit.
The only problem with this construction is that blow-ups glue in a projective line, so X1 is not affine. Let us correct this by gluing in an affine line instead (so our scheme will be an open subset in what was described above).
Here's an algebraic description:
For every kge0, let Ak be the following ring: its elements are collections of
polynomials piinmathbbC[x] where i=0,dots,2k such that pi(1)=pi+1(0).
Set Xk=Spec(Ak). X is a union of 2k+1 affine lines that meet transversally in a chain. (It may be better to index polynomials by i/2k, but the notation gets confusing.)
Define a morphism AktoAk+1 by
(p0,dots,p2k)mapsto(p0,p0(1),p1,p1(1),dots,p2k)
(every other polynomial is constant). This identifies Ak with a subring of Ak+1.
Let A be the direct limit of Ak (basically, their union). Set X=Spec(A). For every
k, we have a natural embedding AktoA, that is, a map XtoXk.
Each Ak is connected but not integral; this implies that A is connected but not integral. It remains to show that A is locally integral.
Take f,ginA with fg=0 and xinX. Let us construct a neighborhood of x on which one of f and g vanishes. Choose k such that f,ginAk−1 (note the k−1 index).
Let y be the image of x on Xk. It suffices to prove that y has a neighborhood on
which either f or g (viewed as functions on Xk) vanishes.
If y is a smooth point of Xk (that is, it lies on only one of the 2k+1 lines), this is obvious. We can therefore assume that y is one of the 2k singular points, so two components of Xk pass through y. However, on one of these two components (the one with odd index), both f and g are constant, since they are pullbacks of functions on Xk−1. Since fg=0 everywhere, either f or g (say, f) vanishes on the other component.
This implies that f vanishes on both components, as required.
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