That is a pretty terse proof! Let me give an outline of a proof that I know. First, one could deduce the statement from a more general:
Theorem 1: Let $R$ be a regular local ring, $E$ be a reflexive $R$-module locally free on $U_R$, the punctured spectrum such that $E$ has no free direct summand. Then one can find a free module $T$ and a filtration:
$$Eoplus T = F_0 supseteq F_1 supseteq cdots F_N =0$$
with $F_i/F_{i+1}$ a syzygy of $k=R/m$.
Why is this local statement implies what you want?
Let $A=k[x_0,cdots, x_n],m=(x_0,cdots,x_n), X=Proj(A)=mathbb P^n, R=A_m$. There is natural functor from the category of vector bundles on $X$ to that of vector bundles on $U_R$, which is the same as the category of reflexive $R$-modules which are locally free on $U_R$. This is used by Horrocks all the time and is explained in Section 9 of his paper: "Vector bundles on punctured spectrum of a regular local ring".
A proof of Theorem 1 can be found in Chapter 5 (theorem 5.2) of the book "Syzygy" by Evans-Griffith. A brief outline in case you can't find the book:
As suggested in the paper you quoted, one starts with a minimal resolution of $E^*$. Then dualizing gives a complex (remember that $E^{**} cong E$ as $E$ is reflexive):
$0 to E to L_0 to L_1 cdots $
whose cohomologies are $Ext^i(E^*,R)$. Let $i>0$ be the smallest number such that $X=Ext^i(E^*,R) neq 0$ Break the l.e.s in to the exact sequences:
$0to E to L_0 to L_1 cdots to L_i to N to 0 (*)$
and $0 to X to N to N/X to 0$. Now build free resolutions for $X$ and $N/X$ and map them onto $(*)$ as in Horseshoe Lemma, stopping at the spot $E$, one gets a s.e.s:
$0 to B to Eoplus T to C to 0$
here $T$ is free and $C$ is a syzygy of $X = Ext^i(E^*,R)$. Repeat if necessary and you have a filtration whose quotient are syzygies of various $ Ext^i(E^*,R)$. But each of this $Ext$ modules has finite length (as $E$ is locally free on $U_R$), so they can be filtered by copies of $k$. Now use the same trick to build a finer filtration whose quotients are syzygies of $k$. Since $R$ is regular, the resolution of $k$ is the Koszul complex, answering your second question.
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